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TP9 A hazardous material assigned to special provision TP9 in Column (7) of the 172.101 Table may only be transported in a portable tank if approved by the Associate Administrator. The Table: provides the proper shipping name or directs the user to the preferred proper shipping name; A37 This entry applies only to a material meeting the definition in 171.8 of this subchapter for self-defense spray. (vi) Except when an organic peroxide is authorized under 173.225(g), if a hazardous material is not assigned a portable tank T Code, the hazardous material may not be transported in a portable tank unless approved by the Associate Administrator. The total mass of lithium batteries contained in any package must not exceed the quantity limits in columns (9A) and (9B) for passenger aircraft or cargo aircraft, as applicable; b. c. Self-propelled vehicles or equipment that also contain an internal combustion engine must be described using the entries Engine, internal combustion, flammable gas powered or Engine, internal combustion, flammable liquid powered or Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as appropriate. The components may be placed in the same outer packaging provided they will not interact dangerously in the event of leakage. 120 The phlegmatized substance must be significantly less sensitive than dry PETN. 12 In concentrations greater than 40 percent, this material has strong oxidizing properties and is capable of starting fires in contact with combustible materials. The present arrangement occurs in such a way that one QA molecule is hydrogen-bonded to four neighboring molecules: two different molecules in one column and other two molecules in another column. 349 Mixtures of hypochlorite with an ammonium salt are forbidden for transport. B66 Each tank must be equipped with gas tight valve protection caps. c. The time between offering the material for transportation at the point of origin, and unloading the material at the destination does not exceed 48 hours. This molecular arrangement is exactly the same as that for dithioketo QA [5]. The map below, compiled from data provided by the Federal Emergency Management Agency (FEMA), is the most accurate nuclear attack map and fallout demonstration available for 2023: (Image courtesy of FEMA and Halcyon Maps) The fallout would rapidly spread, turning targeted cities into whole affected regions. e. When offered for transport in an ammonia dispenser, the receptacles shall be connected to the dispenser in such a way that the assembly is guaranteed to have the same strength as a single receptacle. If the material has a flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this subchapter are applicable. With less than 10 percent formaldehyde, are not subject to this subchapter. Nickel-metal hydride batteries subject to this special provision are subject only to the following requirements: (1) The batteries must be prepared and packaged for transport in a manner to prevent a dangerous evolution of heat, short circuits, and damage to terminals; and are subject to the incident reporting in accordance with 171.16 of this subchapter if a fire, violent rupture, explosion or dangerous evolution of heat (i.e., an amount of heat sufficient to be dangerous to packaging or personal safety to include charring of packaging, melting of packaging, scorching of packaging, or other evidence) occurs as a direct result of a nickel metal hydride battery; and (2) when loaded in a cargo transport unit in a total quantity of 100 kg gross mass or more, the shipping paper requirements of Subpart C of this part, the manifest requirements of 176.30 of this subchapter, and the vessel stowage requirements assigned to this entry in Column (10) of the 172.101 Hazardous Materials Table. Thickness of stainless steel for tank shell and heads for cargo tanks and portable tanks must be the greater of 6.35 mm (0.250 inch) or the thickness required for a tank with a design pressure at least equal to 1.3 times the vapor pressure of the lading at 46 C (115 F). b. Table 1. Used or spent dry batteries of both non-rechargeable and rechargeable designs, with a marked rating up to 9-volt that are combined in the same package and transported by highway or rail for recycling, reconditioning, or disposal are not subject to this special provision or any other requirement of the HMR. A34 Aerosols containing a corrosive liquid in Packing Group II charged with a gas are not permitted for transportation by aircraft. 340 This entry applies only to the vessel transportation of nickel-metal hydride batteries as cargo. Metal: 11A, 11B, 11N, 21A, 21B and 21N, b. The manufacturer must produce technical documentation of the design type, manufacture as well as the tests and their results. B70 If DOT 103ANW tank car tank is used: All cast metal in contact with the lading must have 96.7 percent nickel content; and the lading must be anhydrous and free from any impurities. (iv) The name or symbol of the bottle producer, and the month and year of manufacture, must be marked by embossing, ink-jet printing of permanent ink, or other permanent means on the face or bottom of each bottle, in letters and numbers at least 6 mm (0.2 inch) high. 16 This description applies to smokeless powder and other solid propellants that are used as powder for small arms and have been classed as Division 1.3C, 1.4C and Division 4.1 in accordance with 173.56 of this subchapter. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. Learn more about the eCFR, its status, and the editorial process. Specification 110A500W tanks must be stainless steel. US DOT's Hazardous Materials Regulations (HMR) list more than 3,000 shipping names for regulated materialsfrom acetal to zirconium tetrachloride. TP3 The maximum degree of filling (in %) for solids transported above their melting points and for elevated temperature liquids shall be determined by the following: Where: df and dr are the mean densities of the liquid at the mean temperature of the liquid during filling and the maximum mean bulk temperature during transport respectively. 360 Vehicles powered only by lithium batteries must be described using UN3171, Battery-powered vehicle. Lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit, must be described using UN3536, Lithium batteries installed in a cargo transport unit., 361 Capacitors with an energy storage capacity of 0.3 Wh or less are not subject to the requirements of this subchapter. The standards for CTMVs capable of transporting multiple hazardous materials for blasting in bulk and non-bulk packagings (i.e., a multipurpose bulk truck (MBT)). Orientation markings as described in 172.312(a)(2) are required when liquid hazardous materials may escape due to incorrect orientation. N40 This material is not authorized in the following packagings: a. Others such as copper and silver are available in trace amounts. TP20 This hazardous material must only be transported in insulated tanks under a nitrogen blanket. These batteries are typically used for portable power applications. B49 Tanks equipped with interior heater coils are not authorized. 111 Explosive substances of Division 1.1 Compatibility Group A (1.1A) are forbidden for transportation if dry or not desensitized, unless incorporated in a device. For portable tanks used for the transport of refrigerated liquefied helium and refrigerated liquefied atmospheric gas (except oxygen), the maximum rate at which the tank is filled must not exceed the liquid flow capacity of the pressure relief device rated at 130 percent of the portable tank's design pressure. When column 7 of the Hazardous Materials Table (49 CFR 172.101) includes a special provision code for an entry in the table, the requirement of that code or codes, there may be several of them is in addition to the generalpackaging requirements of173.24and any other applicable packaging requirements in Part 173. An installed inflation cylinder that requires recharging must be filled in accordance with 173.301(l). They must be classified in accordance with the procedure as set out in the Manual of Tests and Criteria, part III, section 39 (IBR, see 171.7 of this subchapter). 135 Internal combustion engines installed in a vehicle must be described using Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as appropriate. IBCs must have a device to allow venting. TP2 a. Radiation detectors transported as individual components must be transported as follows: (1) They must be packed in a sealed intermediate plastic liner with sufficient absorbent or adsorbent material to absorb or adsorb the entire gas contents. Formaldehyde solutions not containing methanol and not meeting the Class 3 flammable liquid criteria must be described using a different proper shipping name. Molten sulfur must be marked as required by 172.325 of this subchapter. The maximum degree of filling must not exceed the degree of filling determined by the following: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and. TP10 A lead lining, not less than 5 mm thick, which shall be tested annually, or another suitable lining material approved by the competent authority, is required. Each tank must be equipped with pressure relief devices conforming to the following requirements: 1 Total venting capacity in standard cubic feet hour (S.C.F.H.) 337 Authorizes the use of regulated waste containers manufactured prior to October 1, 2006 to be marked with the alternative shipping name of Regulated medical waste, UN3291 and arrows that deviate as prescribed in 172.312(a)(2) in that they may be black or white. The lithium batteries must meet the requirements of 173.185(a) and contain the necessary systems to prevent overcharge and over discharge between the batteries. TP8 A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous material transported is greater than 0 C (32 F). The total weight of the explosive contents of the shaped charges assembled in the guns does not exceed 90.5 kg (200 pounds) per vehicle; and. metal other than steel or aluminum (50N). 149 When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to 5 L (1.3 gallons). Stacking is permitted two or more levels high to achieve maximum allowable utilization of the designated vehicle, rail car weight, or intermodal freight container weight or vessel hold volume. 123 Any explosives, blasting, type C containing chlorates must be segregated from explosives containing ammonium nitrate or other ammonium salts. (b) Preparation for transport. N85 Packagings certified at the Packing Group I performance level may not be used. A60 Sterilization devices, when containing less than 30 mL per inner packaging with not more than 150 mL per outer packaging, may be transported in accordance with the provisions in 173.4a, irrespective of 173.4a(b), provided such packagings were first subjected to comparative fire testing. Use the above summary to assist you in reviewing the special provisions applicable to the HazMat you offer for transportation. W100 Non-bulk flexible, fibreboard or wooden packagings must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. (7) Special Provisions (172.102) IB8, IP2, IP4 d. A chemical under pressure with components meeting the properties of: Class 1 (explosives); Class 3 (liquid desensitized explosives); Division 4.1 (self-reactive substances and solid desensitized explosives); Division 4.2 (substances liable to spontaneous combustion); Division 4.3 (substances which, in contact with water, emit flammable gases or toxic gases); Division 5.1 (oxidizing substances); Division 5.2 (organic peroxides); Division 6.2 (Infectious substances); or, Class 7 (Radioactive material), must not be offered for transportation under this description. (2) They must be packed in strong outer packagings and the completed package must be capable of withstanding a 1.8 meter (5.9 feet) drop without leakage of gas contents from detectors. f. Flexible: 13H2, 13H3, 13H4, 13H5, 13L2, 13L3, 13L4, 13M1 and 13M2 (flexible IBCs must be sift-proof and water resistant or must be fitted with a sift-proof and water resistant liner). For transportation by aircraft, articles, machinery, or apparatus, may not contain any material forbidden for transportation by passenger or cargo aircraft. 167 These storage systems must always be considered as containing hydrogen. here. In addition, the material also must be covered with an inert gas or the container must be filled with water to the tank's capacity. Based on the volatility class determined by using ASTM D 439 and the Reid vapor pressure (RVP) of the particular gasoline, the maximum lading pressure and maximum ambient temperature permitted during the loading of gasoline may not exceed that listed in Table I. Quantities of not more than 500 g per package with not less than 10 percent water by mass may also be classed in Division 4.1, provided a negative test result is obtained when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). The vacant space (outage) may be charged with a nonflammable nonliquefied compressed gas if the pressure in the cylinder or sphere at 55 C (130 F) does not exceed 125 percent of the marked service pressure. The tank car specification may be marked to indicate a test pressure of 13.79 Bar (200 psig). There you have it! The packaging shall be designed for a working temperature of at least 121 C (250 F). . 108 Fireworks must be so constructed and packaged that loose pyrotechnic composition will not be present in packages during transportation. It is shown that it does not pose a significant risk in transportation; b. However, button cell batteries installed in equipment (including circuit boards) need not be considered; and, c. The shipping paper must indicate UN 3091 Lithium metal batteries packed with equipment or UN 3481 Lithium ion batteries packed with equipment, as appropriate. This provision may be used for both domestic and international shipments. The adsorbent or absorbent material shall not meet the definition or criteria for inclusion in Classes 1 to 8; c. The maximum contents of a receptacle shall be 10 kg of ammonia; and. Codes in Column 7 may be numbers, or a combination of letters and numbers. The cargo transport unit shall display the UN number in a manner in accordance with 172.332 of this subchapter and be placarded on two opposing sides. If you work for a Federal agency, use this drafting TP30 This hazardous material may only be transported in insulated tanks. A5 Solids having an inhalation toxicity of Packing Group I are not permitted on passenger aircraft and may not exceed a maximum net quantity per package of 15 kg (33 pounds) on cargo aircraft. Refrigerated liquefied gases that are authorized to be transported in portable tanks are specified in tank instruction T75. The outside of each package must be plainly marked ARTICLES, EXPLOSIVES, N.O.S. 109 Rocket motors must be nonpropulsive in transportation unless approved in accordance with 173.56 of this subchapter. B53 Packagings must be made of either aluminum or steel. If unlined tanks are washed out with water, they must be repassivated prior to return to service. 6. The toy plastic or paper caps must be in the form of sheets, strips, rolls, or individual caps; b. B82 Cargo tanks and portable tanks are not authorized. Decomposition can be initiated by heat, moisture or by impurities (e.g., powdered metals (iron, manganese, cobalt, magnesium)). The packing group assignment and packaging must be approved by the Associate Administrator for Hazardous Materials Safety on the basis of the criteria in 173.21 of this subchapter and the package type used for the Series 6(c) test. 70 Black powder that has been classed in accordance with the requirements of 173.56 of this subchapter may be reclassed and offered for domestic transportation as a Division 4.1 material if it is offered for transportation and transported in accordance with the limitations and packaging requirements of 173.170 of this subchapter. After filling, each glass inner packaging must be determined to be leak-tight by placing the glass inner packaging in a hot water bath at a temperature and for a period of time sufficient to ensure that an internal pressure equal to the vapor pressure of ethylene oxide at 55 C is achieved. Use the navigation links in the gray bar above to view the table of contents that this content belongs to. A11 For combination packagings, when metal inner packagings are permitted, only specification cylinders constructed of metals which are compatible with the hazardous material may be used. B61 Written procedures covering details of tank car appurtenances, dome fittings, safety devices, and marking, loading, handling, inspection, and testing practices must be approved by the Associate Administrator before any single unit tank car tank is offered for transportation. N36 Aluminum or aluminum alloy construction materials are permitted only for halogenated hydrocarbons that will not react with aluminum. However this examination is required when the conditions of 180.605(f) are met. You are using an unsupported browser. 162 This material may be transported under the provisions of Division 4.1 only if it is packed so that at no time during transport will the percentage of diluent fall below the percentage that is stated in the shipping description. 114 Jet perforating guns, charged, oil well, without detonator may be reclassed to Division 1.4 Compatibility Group D (1.4D) if the following conditions are met: a. Each portable tank constructed of metal must be fitted with a pressure-relief device consisting of a reclosing spring loaded type, a frangible disc or a fusible element. All openings must be closed with gasketed blank flanges or vapor tight threaded closures. These provisions apply only to transportation by rail. Oxygen cylinders with installed actuating cartridges as prepared for transportation must have an effective means of preventing inadvertent activation. B11 Tank car tanks must have a test pressure of at least 2,068.5 kPa (300 psig). Bulk outer packagings must be liquid tight through design or by the use of lining materials. Batteries contained in devices must be securely installed. TP17 Only inorganic non-combustible materials may be used for thermal insulation of the tank. B7 Safety relief devices are not authorized on multi-unit tank car tanks. information or personal data. 21 This material must be stabilized by appropriate means (e.g., addition of chemical inhibitor, purging to remove oxygen) to prevent dangerous polymerization (see 173.21(f) of this subchapter). user convenience only and is not intended to alter agency intent full text search results 121 This substance, when containing less alcohol, water or phlegmatizer than specified, may not be transported unless approved by the Associate Administrator. These detectors must have a minimum burst pressure of 1800 kPa as demonstrated by design type qualification testing; and. The adsorption or absorption presents the following properties: (1) The pressure at a temperature of 20 C (68 F) in the receptacle is less than 0.6 bar (60 kPa); (2) The pressure at a temperature of 35 C (95 F) in the receptacle is less than 1 bar (100 kPa); (3) The pressure at a temperature of 85 C (185 F) in the receptacle is less than 12 bar (1200 kPa). For transportation of new lighter design samples for examination and testing, see 173.308(b)(2). (You can unsubscribe anytime), Learn More About USDOT/HazMat Transportation, generalpackaging requirements of173.24, Frequently Asked Questions Regarding the Regulations of the Resource Conservation and Recovery Act. 105 The word Agents may be used instead of Explosives when approved by the Associate Administrator. Samples taken at random must withstand the prescribed tests without breakage or leakage. c. The equipment, and machinery or apparatus articles conforms with 173.222 of this subchapter. B15 Packagings must be protected with non-metallic linings impervious to the lading or have a suitable corrosion allowance. a. When a specific portable tank instruction is specified by a T Code in Column (7) of the 172.101 Table for a specific hazardous material, a specification portable tank conforming to an alternative tank instruction may be used if: (A) The alternative portable tank has a higher or equivalent test pressure (for example, 4 bar when 2.65 bar is specified); (B) The alternative portable tank has greater or equivalent wall thickness (for example, 10 mm when 6 mm is specified); (C) The alternative portable tank has a pressure relief device as specified in the T Code. 172-29, 41 FR 15996, Apr. 65 The group of alkaline earth metals includes magnesium, calcium, strontium, and barium. In addition, for solid materials, special provision B54 applies. 35 Antimony sulphides and oxides which do not contain more than 0.5 percent of arsenic calculated on the total mass do not meet the definition of Division 6.1. The chemical under pressure must be classed based on the hazard characteristics of the components in the propellant; the liquid; or the solid. Portable tanks must be hydraulically tested and internally inspected at intervals not exceeding 2.5 years. The mixture for suspensions and gels typically has the following composition: 60-85% ammonium nitrate; 0-5% sodium or potassium perchlorate; 0-17% hexamine nitrate or monomethylamine nitrate; 5-30% water; 2-15% fuel; 0.5-4% thickening agent; 0-10% soluble flame suppressants; and trace additives. However, the design stress limits may not exceed 25 percent of the stress for 0 temper at the maximum design temperature of the cargo tank, as specified in the Aluminum Association's Aluminum Standards and Data (IBR, see 171.7 of this subchapter). (6) The rate of oxygen release from the outer packaging does not exceed 15 mL per hour. W10 When offered for transportation by vessel, the use of Large Packagings (see 171.8 of this subchapter) is prohibited. N43 Metal drums are permitted as single packagings only if constructed of nickel or monel. 2 Except when authorized under Special Provision 41. A current copy of CGA pamphlet, CGA C-6 must be available at the facility servicing the life-saving appliance. For the purpose of this special provision, vehicles are self-propelled apparatus designed to carry one or more persons or goods. The batteries must be securely attached to the interior structure of the cargo transport unit (e.g., by means of placement in racks, cabinets, etc.) N91 The use of a non specification sift-proof, non-bulk, metal can with or without lid, or a non specification sift-proof, non-bulk fiber drum, with or without lid is authorized when transporting coal tar pitch compounds by motor vehicle or rail freight. 134 This entry applies only to vehicles powered by wet batteries, sodium batteries, lithium metal batteries or lithium ion batteries, and equipment powered by wet batteries or sodium batteries that are transported with these batteries installed. This entry may only be used for the transport of non-activated batteries that contain dry potassium hydroxide and that are intended to be activated prior to use by the addition of an appropriate amount of water to the individual cells. The battery has been tested as a primary lithium battery; and. The tank car specification may be marked to indicate a test pressure of 13.79 Bar (200 psig). Any glass inner packaging showing evidence of leakage, distortion or other defect under this test must not be transported under the terms of this special provision; b. A14 This material is not authorized to be transported as a limited quantity or consumer commodity in accordance with 173.306 of this subchapter when transported aboard an aircraft.